This article provides an example for getting started with the Active Directory service monitor.
Host: <AD hostname>
Port: 389
Password: <password from user listed in bind string>
Base: CN=Users,DC=domain,DC=com
Bind: CN=Craig Finn,CN=Users,DC=domain,DC=com
Attribute: sAMAccountName
Replace CN=Craig Finn with the user account you wish to query. If you are not completely familiar with the hierarchy of your AD setup, there are free AD browser tools available such as AD Explorer, which is available at the Microsoft Technet website.